A Frustrated Lewis Pair Based on a Cationic Aluminum Complex and Triphenylphosphine
نویسندگان
چکیده
منابع مشابه
Frustrated Lewis pair behavior of a neutral scandium complex.
An easily-accessible neutral scandium complex Sc[OC(CH3)2CH2PPh2][O-2,6-tBu2-C6H3]2[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.
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ژورنال
عنوان ژورنال: Organometallics
سال: 2016
ISSN: 0276-7333,1520-6041
DOI: 10.1021/acs.organomet.5b00927